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ZEONET® PB

Adhesion improver for FKM

In industrial utilization of FKM, combination of FKM and NBR may be required though FKM is difficult to adhere to NBR.
In this case, ZEONET® PB exhibits remarkable improvement of adhesion between FKM and NBR under their cross-linking process. In this procedure, ZEONET® PB is applied not to FKM but to NBR for its curing system.
ZEONET® PB is compatible with any type of cross-linking system for FKM, such as poly-ol, amine or litharge system. For NBR cure, both curing agent of sulfur and peroxide are applicable to this coupling method by ZEONET® PB.
ZEONET® PB is also effective for adhesion of FKM and ECO.

Adhesion test of FKM and PVC modified NBR

FKM
Viton® VTR9160 100
Bisphenol F Originally contained in Viton® VTR9160
MgO 6
Ca(OH)2 6
Carbon black: N762 15
PVC modified NBR
  Sulfur cure Peroxide cure
Nipol® DN508 100 100
ZnO#1 5 5
Stearic acid 1 1
Carbon black: N990 30 30
Nipsil VN3 15 15
Thiokol TP95 15 15
A.O.224 2 2
Wax 2 2
Sulfur 1.5 -
TMTD
0.5 -
MBTS 1.5 -
Percumil D-40 - 2

Adhesion test result

NBR cure system Sulfur Peroxide
ZEONET® PB for NBR cure 0 3PHR 0 3PHR
Failure mode at peeling test A.F. M.B. A.F. M.B.
A.F.: Adhesive Failure (failure at interface of FKM and NBR layers)
M.B.: Material Break

Effect of ZEONET® PB on mechanical properties of cured NBR

NBR cure system Sulfur Peroxide
ZEONET® PB for NBR cure 0 3PHR 0 3PHR
Mooney Scorch
@125 degrees C t5 (min.)
16.2 4.8 11.4 9.7
Tensile
properties
Tensile Strength (MPa) 15.6 17.2 16.4 17.3
Elongation (%) 420 190 280 470
100% Modulus (MPa) 3.3 8.2 4.2 3.5
Hardness (Shore A) 71 77 37 44
Compression Set (%)
70hr.s at 100 degrees C
47 67 37 44

  1. This product is developed for industrial purpose. Before using the product for food, medical care, or other special applications, the user should confirm the necessary safety measures and precautions specific uses.
  2. The user must comply with the instructions provided in the Material Safety Data Sheet (MSDS).
  3. Information contained in this publication is accurate to the best knowledge and belief of Tokyo Zairyo Co., Ltd. and is subject to change as new information available. This document is provided for informational purpose only, and does not give any warranties or guarantees regarding the performance or quality of the product.